Robuta

https://pubs.rsc.org/en/Content/ArticleLanding/2022/OB/D2OB00410K Phosphine addition to dehydroalanine for peptide modification - Organic & Biomolecular Chemistry... Thiols are a functional group commonly used for selective reactions in a biochemical setting because of their high nucleophilicity. Phosphorus nucleophiles can... peptide modificationphosphineadditionorganicbiomolecular https://pubmed.ncbi.nlm.nih.gov/17685371/?dopt=Abstract A biosynthetic route to dehydroalanine-containing proteins A biosynthetic route to dehydroalanine-containing proteins routecontainingproteins